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BIOENERGY TECHNOLOGIES OFFICE  
3
R&D Challenges for Bio-Oil  
Intermediates  
Integration in Traditional  
Refineries  
Develop better catalysts or processes  
for removing oxygen and other  
impurities  
Successfully integrating biomass  
product streams for further processing  
in traditional petroleum refineries would  
provide refineries with a secure, domestic  
feedstock. Researchers are investigating  
compatibility criteria for crude bio-oils,  
biofuel intermediates, and finished  
hydrocarbon biofuels at various insertion  
points. The goal is to produce biomass-  
based feeds that are identical (at the  
molecular level) to products now found  
in the traditional petroleum refining  
product chain.  
Improve processes for stabilizing  
bio-oils  
Improve catalysts for upgrading bio-  
oils into finished fuels.  
Pathway to Diverse  
Biofuels and Benefits  
Thermochemical processing provides an  
opportunity to produce advanced biofuels  
that deliver diverse benefits to the nation.  
These benefits vary by process and end  
product, providing flexibility in meeting  
market needs. Benefits include:  
BETO research is helping to define  
feedstock criteria and blending  
formulas that will enable reliable  
thermochemical processing.  
For successful integration, the biomass  
feed streams must be able to meet rigor-  
ous criteria. More specifically, they will  
need to be low in oxygen, blend well with  
petroleum, and be free of contaminants  
that could poison the refinery catalysts or  
degrade the product.  
Photo: Art Wiselogel/NREL/04195  
Climate Change: On a life-cycle basis,  
advanced biofuels produced via ther-  
mochemical conversion could reduce  
greenhouse gases by 50% or more,  
relative to conventional gasoline.  
One challenge to the successful use of  
bioproducts in traditional refineries is the  
need to track Renewable Identification  
Numbers (RINs). These are the serial  
numbers assigned to batches of biofuel,  
as required by the Environmental  
Infrastructure Compatibility:  
Although bio-oils can be corrosive  
prior to upgrading, the resulting  
Protection Agency. Companies that  
refine, import, or blend fossil fuels are  
periodically required to submit a number  
of RINs as evidence that they are doing  
their part in meeting national biofuels  
production targets. A system is needed  
for reliability tracking RINs when inter-  
mediate products are transferred between  
biorefineries and traditional refineries.  
advanced biofuels are generally com-  
patible with the existing fuel delivery  
infrastructure (pipelines, tanks, pumps,  
blending facilities, vehicles, etc.).  
BETO is working to better understand  
the physical properties, reactivities,  
and compatibilities of biofuel  
intermediates for finishing in  
traditional petroleum refineries.  
Photo: David Parsons/NREL/05049  
Energy Security: Domestic biofuels  
diversify the energy portfolio and  
decrease U.S. dependence on foreign  
sources of energy. Biorefineries may  
potentially serve as regionally inde-  
pendent energy facilities, improving  
energy security and resilience.  
Researchers are defining criteria for the insertion of biorefinery intermediates into traditional refineries.  


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